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Formic acid

CAS 64-18-6CH2O246.025 g/mol

Formic acid is the simplest carboxylic acid, containing a single carbon. Occurs naturally in various sources including the venom of bee and ant stings, and is a useful organic synthetic reagent. Principally used as a preservative and antibacterial agent in livestock feed. Induces severe metabolic acidosis and ocular injury in human subjects. It has a role as a metabolite, an antibacterial agent, a solvent, a protic solvent and an astringent. It is a conjugate acid of a formate.

IUPAC: formic acid

Formic acid molecular structure

PubChem

Physical & Chemical Properties

Physical and chemical properties
Melting Point47.1 °F (NTP, 1992)
Boiling Point213.3 °F at 760 mmHg (NTP, 1992)
Density1.22 at 68 °F (USCG, 1999) - Denser than water; will sink
Solubilitygreater than or equal to 100 mg/mL at 70 °F (NTP, 1992)
Flash Point156 °F (NTP, 1992)
Vapor Pressure35 mmHg at 68 °F ; 200 mmHg at 142.5 °F (NTP, 1992)
AppearanceFormic acid appears as a colorless liquid with a pungent odor. Flash point 156 °F. Density 10.2 lb / gal. Corrosive to metals and tissue.

Data: PubChem · Last updated: 4/20/2026

GHS Classification

No GHS classification data available.

Classification data is sourced from ECHA.

Regulatory Compliance

TSCA

Listed

note: Status based on EPA TSCA Active Inventory · inventory name: TSCA Chemical Substance Inventory

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SVHC

Not Listed

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FDA GRAS

Not Listed

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HS Code(s): 2915

Data: UN Comtrade

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